Palladium‐Catalysed C‐H Alkenylation of Arenes with Alkynes: Stereoselective Synthesis of Vinyl Chlorides via a 1,4‐Chlorine Migration

Date: 2018- 11- 07 hits: Author: 陈洁

A directing groupfree, ligandpromoted palladiumcatalysed CH arylation of internal alkynes with simple arenes was developed, and alkenyl chlorides via 1,4chlorine migration or trisubstituted alkenes were produced in moderate to good yields depending on the type of alkyne.

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